WebCyclotriphosphazene derivatives containing a P–NHR group in the side-chain react in the presence of a strong base to form stable intermolecular bridged products. Reaction of sodium hydride with mono-spiro cyclophosphazene derivatives having a P–NH group, N 3 P 3 Cl 4 [O(CH 2) 3 NH], (1a) or N 3 P 3 Cl 4 [CH 3 N(CH 2) 3 NH], (1b) leads to formation … WebNov 5, 2024 · The nature of cyclophosphazene-adducted compounds usually depends both on the phosphazene base and the corresponding Lewis acid. For example, for the N 6 P 6 (NMe 2) 12 .CuCl 2, Lewis acid is not bonded to a particular ring atom. However, it is located on the ring and is attached to more than one nitrogen atom [ 27 ].
Journal of the Chemical Society, Dalton Transactions
WebFeb 11, 2024 · Three new 2-component unsubstituted ( 4P), diiodo- ( 5P), and dibromo- ( 6P) distyryl-BODIPY-bridged cyclotriphosphazene dimers were designed and … WebSep 28, 2024 · The thermal degradation and flame retardancy effect between ionic liquid-modified graphene and hexaphenoxy cyclotriphosphazene on epoxy resin (EP) was investigated using thermogravimetric analysis, differential thermogravimetric analysis, thermogravimetric analysis-infrared spectrometry (TGA-FTIR) and the char residue … dfw haunted houses 2021
Cyclotriphosphazene-bridged periodic mesoporous organosilica …
WebNov 1, 2024 · In this study, we synthesized cyclotriphosphazene-bridged periodic mesoporous organosilica (PMOPZ) for the first time. Afterwards, PMOPZ was integrated with CNF to design an anisotropic composite foam via the unidirectional freeze-drying … WebTriple diamino-bridged cyclotriphosphazene (1) was reacted in a 1:8 stoichiometry with the sodium derivatives of long-chain diols [1-octanol, 1-decanol, 1-dodecanol, 1-hexadecanol] tetrahydrofuran (THF) at room temperature to form hexa-substituted cyclotriphosphazene derivatives (2, 3, 4 and 5, respectively), whose mesomorphic … chwe mlynedd